A highly selective arene hydrogenation catalyst that operates in ionic liquid

被引：84

作者：

Boxwell, CJ

Dyson, PJ ^{[1
]}

Ellis, DJ

Welton, T

机构：

[1] Ecole Polytech Fed Lausanne, Inst Chim Mol & Biol, BCH, CH-1015 Lausanne, Switzerland

[2] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

[3] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 32期

关键词：

D O I：

10.1021/ja026361r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and structural characterization of [Ru(η6-p-cymene)(η2-TRIPHOS)Cl][PF6] is described. The complex is a highly active, homogeneous arene hydrogenation catalyst that is selective toward the hydrogenation of aromatic rings in preference to alkenes, as demonstrated by the hydrogenation of allylbenzene to allylcyclohexane. The catalyst operates in both dichloromethane and ionic liquids and undergoes no decomposition in the latter solvent. Copyright © 2002 American Chemical Society.

引用

页码：9334 / 9335

页数：2

共 24 条

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