Samarium(III) catalyzed one-pot construction of coumarins

被引:107
作者
Bahekar, SS
Shinde, DB [1 ]
机构
[1] Dr Babasaheb Ambedkar Marathwada Univ, Dept Chem Technol, Aurangabad 431004, Maharashtra, India
[2] Natl Cheang Kung Univ, Dept Chem, Tainan, Taiwan
关键词
coumarins; Pechmann condensation; Lewis acid catalysts;
D O I
10.1016/j.tetlet.2004.09.013
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Samarium(III) nitrate hexahydrate as a catalyst is used as an alternative to conventional acid catalysts in the von Pechmann condensation of phenols with ethyl acetoacetate leading to the formation of coumarin derivatives. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:7999 / 8001
页数:3
相关论文
共 27 条
[21]   VINYL RADICALS . STEREOSELECTIVITY IN HYDROGEN ATOM TRANSFER TO EQUILIBRATED ISOMERIC VINYL RADICALS [J].
SINGER, LA ;
KONG, NP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (22) :5213-&
[22]   A NEW 1-STEP SYNTHESIS OF SUBSTITUTED COUMARINS [J].
WOODS, LL ;
SAPP, J .
JOURNAL OF ORGANIC CHEMISTRY, 1962, 27 (10) :3703-&
[23]   A new and efficient route to 4-carboxymethylcoumarins mediated by vinyltriphenylphosphonium salt [J].
Yavari, I ;
Hekmat-Shoar, R ;
Zonouzi, A .
TETRAHEDRON LETTERS, 1998, 39 (16) :2391-2392
[24]   beta-Diketone synthesis by reaction of alpha-haloketones with acid chlorides or acid anhydrides promoted by samarium triiodide [J].
Ying, TK ;
Bao, WL ;
Zhang, YM .
SYNTHETIC COMMUNICATIONS, 1996, 26 (15) :2905-2909
[25]   A facile synthetic route to alpha-selenoketones promoted by SmI2 or SmI3 [J].
Ying, TK ;
Bao, WL ;
Zhang, YM .
SYNTHETIC COMMUNICATIONS, 1996, 26 (08) :1517-1523
[26]  
YU YP, 1993, TETRAHEDRON LETT, V34, P4547
[27]  
Zahradnik M., 1992, The Production and Application of Fluorescent Brightening Agents