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Fabrication of a Metal Membrane on a Perforated Polymer Substrate by Palladium Aerosol Activation and Subsequent Electroless Plating
被引:13
作者:
Byeon, Jeong Hoon
[3
]
Hwang, Jungho
[1
,2
]
机构:
[1] Yonsei Univ, Sch Mech Engn, Seoul 120749, South Korea
[2] Yonsei Univ, Yonsei Ctr Clean Technol, Seoul 120749, South Korea
[3] Samsung Elect Co Ltd, Digital Printing Div, Suwon 443742, South Korea
关键词:
metal membrane;
perforated PTFE substrate;
spark generation;
Pd aerosol activation;
electroless plating;
COMPOSITE MEMBRANES;
PERVAPORATION DEHYDRATION;
POROUS POLYMER;
DEPOSITION;
SURFACE;
SILVER;
FILMS;
MECHANISM;
MICROSTRUCTURE;
NANOPARTICLES;
D O I:
10.1021/am8001742
中图分类号:
TB3 [工程材料学];
学科分类号:
082905 [生物质能源与材料];
摘要:
Fabrication of a metal membrane on a perforated flexible poly(tetrafluoroethylene) (PTFE) substrate was developed by employing spark-generated palladium (Pd) aerosol activation and the subsequent electroless plating of Pd. After aerosol activation, Pd agglomerates of spark-generated primary particles (similar to 2.6 nm in diameter) with a face centered-cubic structure were deposited uniformly on the PTFE substrate. Homogeneous Pd particles with an average size of 188nm were tightly packed together to form a Pd membrane after Pd plating. The average plating rate of Pd during 30 min of plating at an activation intensity of 25 mu g/cm(2) was 14.2 mu g/cm(2).min.
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页码:261 / 265
页数:5
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