Preparation and Multi-Characterization of Plasma Polymerized Allylamine Films

被引：48

作者：

Abbas, Abdennour ^{[1
]}

Vivien, Celine ^{[1
]}

Bocquet, Bertrand ^{[2
]}

Guillochon, Didier ^{[3
]}

Supiot, Philippe ^{[1
]}

机构：

[1] Univ Lille 1, Lab Proc Engn React Fluids Mat Interact, EA 3571, F-59655 Villeneuve Dascq, France

[2] CNRS, Inst Elect Microelect & Nanotechnol, UMR 8520, F-59652 Villeneuve Dascq, France

[3] Polytech Lille, Lab Biol Proc Enzymat & Microbial Engn, EA 1026, F-59655 Villeneuve Dascq, France

来源：

PLASMA PROCESSES AND POLYMERS | 2009年 / 6卷 / 09期

关键词：

allylamine; plasma polymerization; primary amine groups; radio-frequency glow discharges (RFGD); thin film; SURFACE MODIFICATION; ACRYLIC-ACID; AMINE; DEPOSITION; COATINGS; ADHESION; DENSITY; SUPPORT; LAYER;

D O I：

10.1002/ppap.200900016

中图分类号：

O59 [应用物理学];

学科分类号：

070305 [高分子化学与物理];

摘要：

Plasma polymerized allylamine (ppAA) films were deposited in a radio-frequency glow discharge plasma reactor using a continuous-wave mode and varying the discharge power from 15 to 125 W. The deposition rate reached 26 nm . min(-1) and was constant within at least half an hour of process. The chemical structure and elemental composition of the deposited films were investigated by Fourier transform infrared and X-ray photoelectron spectroscopies, whereas surface properties were analyzed by atomic force microscopy and surface free energy measurement. A special focus is given to the stability of ppAA in aqueous media and primary amine quantification. The use of fluorescent microscopy and UV-Visible spectroscopy enabled us to detect and quantify the primary amine, respectively. All the studied parameters varied widely with enhanced power with a transition point around 50 W. Over this value, the results remain relatively unchanged.

引用

页码：593 / 604

页数：12

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