Intramolecular folding of triblock copolymers via quadrupole interactions between poly(styrene) and poly(pentafluorostyrene) blocks

被引：46

作者：

Lu, Jie ^{[1
]}

ten Brummelhuis, Niels ^{[1
]}

Weck, Marcus ^{[1
]}

机构：

[1] NYU, Dept Chem, Inst Mol Design, New York, NY 10003 USA

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 47期

关键词：

AROMATIC STACKING INTERACTIONS; SYNTHETIC-POLYMERS; ARENE INTERACTIONS; HELICAL POLYMERS; CHARGE-TRANSFER; POLYMERIZATION; FOLDAMERS; BEHAVIOR;

D O I：

10.1039/c4cc01840k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

beta-Hairpin formation is one of the fundamental folding actions in biomacromolecules. We present a linear triblock copolymer synthesized via reversible addition-fragmentation chain transfer (RAFT) polymerization, that is able to mimic on a very basic level hairpin formation by using pi-pi stacking interactions between phenyl and 2,3,4,5,6-pentafluorophenyl residues.

引用

页码：6225 / 6227

页数：3

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