Stereoselective synthesis of chiral coordination polymers with partial control of the rigid main chain topology

被引：28

作者：

Chen, JB ^{[1
]}

MacDonnell, FM ^{[1
]}

机构：

[1] Univ Texas, Dept Chem & Biochem, Arlington, TX 76019 USA

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 24期

关键词：

D O I：

10.1039/a906645d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The condensation polymerization between the appropriate enantiomers of [Ru(1,10-phenanthroline-5,6-dione)(2)-(bpy)](2+) 1 and [Ru(1,10-phenanthroline-5,6-diamine)(2)-(bpy)](2+) 2 in meta-cresol gave the homochiral coordination polymers Delta-3 and Lambda-3 as well as the meso polymer, Delta Lambda-3, which exhibit rigid, ribbon-like structures with different main chain topologies.

引用

页码：2529 / 2530

页数：2

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