Synthesis of porphyrins bearing trans-thiols

被引：30

作者：

Jagessar, RC

Tour, JM

机构：

[1] Rice Univ, Dept Chem, Houston, TX 77005 USA

[2] Rice Univ, Ctr Nanoscale Sci & Technol, Houston, TX 77005 USA

[3] Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA

来源：

ORGANIC LETTERS | 2000年 / 2卷 / 02期

关键词：

D O I：

10.1021/ol9911728

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] A route to porphyrins bearing trans-thiols is described using a thioacetyl containing aldehyde or a thioacetyl containing dipyrromethane in the presence of catalytic BF3. OEt2 followed by oxidation. Metal complexation and ammonium hydroxide induced acetyl removal provides a route to these important molecular systems for future electronics experiments in which the thiols would serve as the adhesion points to gold probes.

引用

页码：111 / 113

页数：3

共 24 条

[21] Molecular scale electronics: A synthetic/computational approach to digital computing [J].