Dendrimers based on a three-dimensionally disposed AB4 monomer

被引:27
作者
Jayakumar, KN [1 ]
Bharathi, P [1 ]
Thayumanavan, S [1 ]
机构
[1] Univ Massachusetts, Dept Chem, Amherst, MA 01003 USA
关键词
D O I
10.1021/ol049147b
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Design and synthesis of a novel class of dendrons based on an AB(4) monomer are described. These dendrons have been evaluated by using dendritic encapsulation of a redox active core. The electrochemical properties of symmetric ferrocene-cored dendrimers show that significant alterations in redox potential and heterogeneous electron-transfer rate constants could be achieved even at lower generations.
引用
收藏
页码:2547 / 2550
页数:4
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