Weakly Coordinating Directing Groups for Ruthenium(II)-Catalyzed C-H Activation

被引：676

作者：

De Sarkar, Suman ^{[1
]}

Liu, Weiping ^{[1
]}

Kozhushkov, Sergei I. ^{[1
]}

Ackermann, Lutz ^{[1
]}

机构：

[1] Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2014年 / 356卷 / 07期

基金：

欧洲研究理事会;

关键词：

C-H activation; directing groups; homogenous catalysis; ruthenium; weak coordination; AEROBIC OXIDATIVE CYCLIZATION; CATALYZED ORTHO-ALKENYLATION; CARBON-HYDROGEN BONDS; AROMATIC KETONES; DIRECT ARYLATIONS; REGIOSELECTIVE SYNTHESIS; BORONIC ACIDS; EASY ROUTE; H/O-H; RUTHENIUM;

D O I：

10.1002/adsc.201400110

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Synthetically useful functional groups, including ketones, amides, carbamates, carboxylic acids, aldehydes or ethers, have been identified as weakly coordinating directing groups in efficient ruthenium(II)-catalyzed CH functionalizations. This strategy set the stage for versatile CH bond olefinations, oxygenations, nitrogenations and oxidative alkyne annulations among others. Thereby, step-economical access to diversely decorated arenes and heteroarenes was provided in a sustainable fashion.

引用

页码：1461 / 1479

页数：19

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