Raman spectra of ion beam sputtered amorphous carbon thin films deposited from camphoric carbon

被引:74
作者
Mominuzzaman, SM
Krishna, KM
Soga, T
Jimbo, T
Umeno, M
机构
[1] Nagoya Inst Technol, Dept Elect & Comp Engn, Showa Ku, Nagoya, Aichi 4668555, Japan
[2] Nagoya Inst Technol, Res Ctr Microstruct Devices, Showa Ku, Nagoya, Aichi 4668555, Japan
[3] Nagoya Inst Technol, Dept Environm Technol & Urban Planning, Showa Ku, Nagoya, Aichi 4668555, Japan
基金
日本学术振兴会;
关键词
amorphous carbon; carbon precursor; heat treatment; Raman spectroscopy; crystallite size;
D O I
10.1016/S0008-6223(99)00107-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Thin films of carbon were deposited on single crystal silicon and quartz substrates by simple ion beam sputtering of camphoric cal bon target, obtained from camphor: a natural source, at room temperature. The as-deposited films were heat treated at different temperatures and the effects of heat treatment on structural modifications were studied in detail by Raman spectroscopy through the evolution of D and G bands. The spectral evolution observed on heat treated samples show progressive formation of crystallites. These structural changes were further correlated with optical gap and fraction of sp(3) bonded carbons present, derived respectively from uv-visible and photoelectron spectroscopies, and the results obtained are discussed and compared with the literature. (C) 1999 Elsevier Science Ltd, All rights reserved.
引用
收藏
页码:127 / 131
页数:5
相关论文
共 33 条
[11]   CHARACTERIZATION OF DIAMOND FILMS BY RAMAN-SPECTROSCOPY [J].
KNIGHT, DS ;
WHITE, WB .
JOURNAL OF MATERIALS RESEARCH, 1989, 4 (02) :385-393
[12]   A phosphorus doped (n-type) carbon boron doped (p-type) silicon photovoltaic solar cell from a natural source [J].
Krishna, KM ;
Soga, T ;
Jimbo, T ;
Umeno, M .
CARBON, 1999, 37 (03) :531-533
[13]   Photovoltaic solar cell from camphoric carbon - A natural source [J].
Krishna, KM ;
Soga, T ;
Mukhopadhyay, K ;
Sharon, M ;
Umeno, M .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 1997, 48 (1-4) :25-33
[14]   RAMAN-SCATTERING FROM ION-IMPLANTED DIAMOND, GRAPHITE, AND POLYMERS [J].
LEE, EH ;
HEMBREE, DM ;
RAO, GR ;
MANSUR, LK .
PHYSICAL REVIEW B, 1993, 48 (21) :15540-15551
[15]   MODEL FOR RAMAN-SCATTERING FROM INCOMPLETELY GRAPHITIZED CARBONS [J].
LESPADE, P ;
ALJISHI, R ;
DRESSELHAUS, MS .
CARBON, 1982, 20 (05) :427-431
[16]   Conductivity and structural studies on disordered amorphous conducting carbon films [J].
Meenakshi, V ;
Sayeed, A ;
Subramanyam, SV .
DISORDERED MATERIALS - CURRENT DEVELOPMENTS -, 1996, 223 :307-310
[17]   Optical absorption and electrical conductivity of amorphous carbon thin films from camphor: A natural source [J].
Mominuzzaman, SM ;
Krishna, KM ;
Soga, T ;
Jimbo, T ;
Umeno, M .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1999, 38 (2A) :658-663
[18]   Semiconducting camphoric carbon tubules [J].
Mukhopadhyay, K ;
Krishna, KM ;
Sharon, M .
CARBON, 1996, 34 (02) :251-264
[19]   A simple method acid new source for getting diamond-like carbon film and polycrystalline diamond film [J].
Mukhopadhyay, K ;
Krishna, KM ;
Sharon, M .
MATERIALS CHEMISTRY AND PHYSICS, 1997, 49 (03) :252-257
[20]   FULLERENES FROM CAMPHOR - A NATURAL SOURCE [J].
MUKHOPADHYAY, K ;
KRISHNA, KM ;
SHARON, M .
PHYSICAL REVIEW LETTERS, 1994, 72 (20) :3182-3185