Tetrahedral frameworks TX2 with T-X-T angle=180° -: Rationalization of the structures of MOF-500 and of MIL-100 and MIL-101

被引:17
作者
O'Keeffe, Michael [1 ]
机构
[1] Arizona State Univ, Dept Chem & Biochem, Tempe, AZ 85287 USA
基金
美国国家科学基金会;
关键词
microporous materials;
D O I
10.1016/j.materresbull.2005.12.013
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
It is shown that the TX2 structures adopted by the giant MOFs MOF-500, MIL-100 and MIL-101 are uniquely determined as a result of the requirement of regular TX4 tetrahedra, T-X-T angles of 180 degrees and appropriate X-T-T-X dihedral angles. (C) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:911 / 915
页数:5
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