What can we learn by squeezing a liquid?

被引:20
作者
Casalini, R.
Capaccioli, S.
Roland, C. M.
机构
[1] USN, Res Lab, Washington, DC 20375 USA
[2] George Mason Univ, Fairfax, VA 22030 USA
[3] Univ Pisa, Dipartimento Fis, Pisa, Italy
[4] Univ Pisa, INFM, Pisa, Italy
[5] CNR, INFM, CRS, SOFT, Rome, Italy
关键词
D O I
10.1021/jp062356o
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 [物理化学]; 081704 [应用化学];
摘要
Relaxation times tau(T,v) for different temperatures, T, and specific volumes, v, collapse to a master curve vs Tu(gamma), with gamma a material constant. The isochoric fragility, m(V), is also a material constant, inversely correlated with gamma. From these experimental facts, we obtain a three-parameter function that accurately fits tau(T,v) data for several glass-formers over the supercooled regime, without any divergence of tau below T-g. Although the values of the three parameters depend on the material, only gamma significantly varies; thus, by normalizing material-specific quantities related to gamma, a universal power law for the dynamics is obtained.
引用
收藏
页码:11491 / 11495
页数:5
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