Azadiene Diels-Alder reactions: Scope and applications. Total synthesis of natural and ent-fredericamycin A

被引：45

作者：

Boger, DL

机构：

[1] Department of Chemistry, Scripps Research Institute, San Diego, CA 92037

来源：

JOURNAL OF HETEROCYCLIC CHEMISTRY | 1996年 / 33卷 / 05期

关键词：

D O I：

10.1002/jhet.5570330508

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A review of our studies of the inverse electron demand Diels-Alder reactions of heteroaromatic and acyclic azadienes is presented and the application of a N-sulfonyl-1-aza-1,3-butadiene [4 + 2] cycloaddition reaction in the total synthesis of natural and ent-fredericamycin A is described in detail.

引用

页码：1519 / 1531

页数：13