Aromatics to polyquinanes:: A general method for the construction of tricyclo[6.3.0.04,8]-and tricyclo[6.3.0.02,6]undecanes

被引：6

作者：

Biju, PJ ^{[1
]}

Rao, GSRS ^{[1
]}

机构：

[1] Indian Inst Sci, Dept Organ Chem, Bangalore 560012, Karnataka, India

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 52期

关键词：

D O I：

10.1016/S0040-4039(99)02026-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The conversion of aromatic compounds to linear and angular triquinanes is described and involves a 5-exo-trig-allyl radical cyclization as the key reaction for constructing the strained ketones 9 and 18, which are then transformed into the quinanes 12 and 23, respectively. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.

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页码：9379 / 9382

页数：4

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