An easy entry to novel early-late oligonuclear transition metal complexes containing π-conjugated systems

被引：23

作者：

Back, S

Frosch, W

del Río, I

van Koten, G

Lang, H

机构：

[1] Tech Univ Chemnitz, Inst Chem, Lehrstuhl Anorgan Chem, D-09111 Chemnitz, Germany

[2] Univ Utrecht, Debye Inst, Dept Met Mediated Synth, NL-3584 CH Utrecht, Netherlands

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 1999年 / 2卷 / 12期

关键词：

heterometallic complexes; conjugated ligand complexes; pi-tweezer complexes; early-late complexes; transition metal complexes; oligonuclear complexes;

D O I：

10.1016/S1387-7003(99)00158-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Heterotrinuclear Ti-Cu-Ru (5) and heterotetranuclear Ti-Cu-Pt-Fe (7) containing complexes are accessible by using {[Ti](C=(CBu)-Bu-t)(2)}CuMe (1) ([Ti] = (eta(5)-C5H4SiMe3)(2)Ti) as key molecule; in 5 and 7, the corresponding early and late transition metal atoms are linked by pi-conjugated organic moieties. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：584 / 586

页数：3

共 27 条

[21] Synthesis and characterization of new ferrocenyl heterobimetallic compounds with high NLO responses [J].