Advances in self-ordering macromolecules and nanostructure design

被引:45
作者
Spontak, RJ
Alexandridis, P
机构
[1] Univ Freiburg, Inst Makromol Chem, D-79104 Freiburg, Germany
[2] N Carolina State Univ, Dept Chem Engn, Riddick Engn Labs 113, Raleigh, NC 27695 USA
[3] N Carolina State Univ, Dept Mat Sci & Engn, Riddick Engn Labs 113, Raleigh, NC 27695 USA
[4] SUNY Buffalo, Dept Chem Engn, Rochester, NY 14620 USA
关键词
D O I
10.1016/S1359-0294(99)00023-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Nanostructured macromolecules, such as block copolymers, elucidate the fundamental principles governing self-organization in soft condensed matter. Significant experimental and theoretical advances regarding complex morphology development in bulk copolymers and their homopolymer blends have recently been achieved. New equilibrium block copolymer morphologies have been reported for copolymers in the super-strong segregation regime, and the pathways by which bicontinuous morphologies in copolymers and copolymer blends form have been identified. Emerging research directions target chemically tailored copolymer systems as designer templates for uniform ceramic nanostructures and field-responsive devices with switchable molecular orientation.
引用
收藏
页码:140 / 146
页数:7
相关论文
共 61 条
[21]   Small-angle X-ray scattering and rheological studies on the ordering process of cylindrical microdomains in a polystyrene-block-polyisoprene copolymer [J].
Hashimoto, T ;
Ogawa, T ;
Sakamoto, N ;
Ichimiya, M ;
Kim, JK ;
Han, CD .
POLYMER, 1998, 39 (8-9) :1573-1581
[22]   Lower and upper critical ordering temperatures in compressible diblock copolymer melts from a perturbed hard-sphere-chain equation of state [J].
Hino, T ;
Prausnitz, JM .
MACROMOLECULES, 1998, 31 (08) :2636-2648
[23]  
KELLER A, 1994, SELF ORDER FORM POLY
[24]   Synthesis of nanoporous silica with new pore morphologies by templating the assemblies of ionic block copolymers [J].
Kramer, E ;
Forster, S ;
Goltner, C ;
Antonietti, M .
LANGMUIR, 1998, 14 (08) :2027-2031
[25]   Effect of pressure on the microphase separation of the symmetric diblock copolymer poly(styrene-block-butadiene) [J].
Ladynski, H ;
De Odorico, W ;
Stamm, M .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1998, 235 :491-495
[26]   Elastic properties of homopolymer-homopolymer interfaces containing diblock copolymers [J].
Laradji, M ;
Desai, RC .
JOURNAL OF CHEMICAL PHYSICS, 1998, 108 (11) :4662-4674
[27]   Interfacial modification as a route to novel bilayered morphologies in binary block copolymer/homopolymer blends [J].
Laurer, JH ;
Smith, SD ;
Samseth, J ;
Mortensen, K ;
Spontak, RJ .
MACROMOLECULES, 1998, 31 (15) :4975-4985
[28]   Bicontinuous morphologies in homologous multiblock copolymers and their homopolymer blends [J].
Laurer, JH ;
Hajduk, DK ;
Dreckotter, S ;
Smith, SD ;
Spontak, RJ .
MACROMOLECULES, 1998, 31 (21) :7546-7549
[29]   Kinetics of microemulsion formation in polymer mixtures [J].
Lee, JH ;
Jeon, HS ;
Balsara, NP ;
Newstein, MC .
JOURNAL OF CHEMICAL PHYSICS, 1998, 108 (13) :5173-5176
[30]   THEORY OF MICROPHASE SEPARATION IN BLOCK CO-POLYMERS [J].
LEIBLER, L .
MACROMOLECULES, 1980, 13 (06) :1602-1617