Synthesis and polymerization of novel N-substituted maleimides containing an oxazoline group

被引：29

作者：

Jiang, LM ^{[1
]}

Ni, HG ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Polymer Sci & Engn, Hangzhou 310027, Peoples R China

来源：

POLYMER BULLETIN | 2004年 / 52卷 / 01期

关键词：

D O I：

10.1007/s00289-004-0251-7

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A novel type of maleimide-based monomers, N-[o-(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)phenyl]maleimide (DMOPMI), (+/-)-N-[o-(4-ethyl-4,5-dihydro-1,3-oxazol -2-yl)phenyl]maleimide ((+/-)-EOPMI), and (R)-N-[o-(4-ethyl-4,5-dihydro-1,3-oxazol-2-yl)phenyl]maleimide ((R)-EOPMI), were synthesized for the first time. Their polymerization behavior was studied briefly by both radical and anionic initiating mechanisms. The results indicated that the addition polymerization takes place mainly in the vinylene group without appreciable side reactions. The polymerization in low polar media tended to increase molecular weights or optical activity of the obtained polymers.

引用

页码：1 / 7

页数：7

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