Synthesis and crystal structure of [PdMe{PPh2NHC(O)Me}{O=C(NH2)Me}][BF4], a palladium complex containing the acetamide ligand

被引：7

作者：

Braunstein, P ^{[1
]}

Frison, C ^{[1
]}

Morise, X ^{[1
]}

机构：

[1] Univ Strasbourg, Chim Coordinat Lab, CNRS, UMR 7513, F-67070 Strasbourg, France

来源：

COMPTES RENDUS CHIMIE | 2002年 / 5卷 / 02期

关键词：

acetamide; acetamidophosphine; crystal structure; palladium;

D O I：

10.1016/S1631-0748(02)01340-1

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of a square planar cationic Pd(II) complex containing the acetamide ligand is described. The complex has been characterised by X-ray diffraction, leading to one of the rare examples of a crystal structure showing an acetamide molecule coordinated to a metal centre and, to the best of our knowledge, the first one with palladium. This complex may be relevant to catalytic reactions, such as the palladium-catalysed amidocarbonylation, in which transient species with O-coordinated acetamide can be formed.

引用

页码：131 / 135

页数：5

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