Tunable full-color-emitting La0.827Al11.9O19.09:Eu2+,Mn2+ phosphor for application to warm white-light-emitting diodes
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Won, Yu-Ho
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机构:Korea Adv Inst Sci & Technol, Dept Mat Sci & Engn, Taejon 305701, South Korea
Won, Yu-Ho
Jang, Ho Seong
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机构:Korea Adv Inst Sci & Technol, Dept Mat Sci & Engn, Taejon 305701, South Korea
Jang, Ho Seong
Im, Won Bin
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机构:Korea Adv Inst Sci & Technol, Dept Mat Sci & Engn, Taejon 305701, South Korea
Im, Won Bin
Jeon, Duk Young
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Korea Adv Inst Sci & Technol, Dept Mat Sci & Engn, Taejon 305701, South KoreaKorea Adv Inst Sci & Technol, Dept Mat Sci & Engn, Taejon 305701, South Korea
Jeon, Duk Young
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Lee, Jeong Soo
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机构:Korea Adv Inst Sci & Technol, Dept Mat Sci & Engn, Taejon 305701, South Korea
Lee, Jeong Soo
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[1] Korea Adv Inst Sci & Technol, Dept Mat Sci & Engn, Taejon 305701, South Korea
[2] LG Elect Inst Technol, LED R&D Lab, Seoul 137140, South Korea
La0.827Al11.9O19.09:Eu2+,Mn2+ showed three emission bands when excited by ultraviolet light. A blue emission originates from Eu2+, whereas both green and red emissions originate from Mn2+. The luminescent mechanism is explained invoking the energy transfer of Eu2+-> Mn2+ and Mn2+(tetrahedral site)-> Mn2+(octahedral site). This energy transfer was confirmed by faster decay times of the blue and green emissions as energy donors. The emitted color of La0.827Al11.9O19.09:Eu2+,Mn2+ can be easily tailored from blue to red through variations of the Mn2+ content. The white-light-emitting diode fabricated via a combination of an ultraviolet light-emitting diode (lambda(peak)=385 nm) with La0.827Al11.9O19.09:Eu2+,Mn2+ showed a warm white light (T-c=3559 K). (c) 2006 American Institute of Physics.