Eu(III)-cyclen-phen conjugate as a luminescent copper sensor:: the formation of mixed polymetallic macrocyclic complexes in water

被引：101

作者：

Gunnlaugsson, T ^{[1
]}

Leonard, JP ^{[1
]}

Sénéchal, K ^{[1
]}

Harte, AJ ^{[1
]}

机构：

[1] Univ Dublin Trinity Coll, Dept Chem, Dublin 2, Ireland

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 07期

关键词：

D O I：

10.1039/b316176e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The cationic cyclen based Eu(III)-phen conjugated 1.Eu was synthesised as a chemosensor for Cu(II), where the recognition in water at pH 7.4 gave rise to quenching of the Eu(III) luminescence and the formation of tetranuclear polymetallic Cu(II)-Eu(III) macrocyclic complexes in solution where Cu(II) was bound by three 1.Eu conjugates.

引用

页码：782 / 783

页数：2

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