Synthesis of Chiraphos via asymmetric hydrogenation of 2,3-bis(diphenylphosphinoyl)buta-1,3-diene

被引：20

作者：

Beghetto, V ^{[1
]}

Matteoli, U ^{[1
]}

Scrivanti, A ^{[1
]}

机构：

[1] Univ Venice, Dipartimento Chim, I-30123 Venice, Italy

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 02期

关键词：

D O I：

10.1039/a908447i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(S,S)-2,3-Bis(diphenylphosphinoyl)butane, an immediate precursor of (S,S)-CHIRAPHOS, can be obtained with 70% de and 71% op via double asymmetric hydrogenation of 2,3-bis(diphenylphosphinoyl)buta-1,3-diene in the presence of Ru-(S)-BINAP catalysts.

引用

页码：155 / 156

页数：2

共 8 条

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