Bent versus linear imido ligands in five-co-ordinate molybdenum complexes

被引:45
作者
Gibson, VC [1 ]
Marshall, EL [1 ]
Redshaw, C [1 ]
Clegg, W [1 ]
Elsegood, MRJ [1 ]
机构
[1] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 22期
关键词
D O I
10.1039/dt9960004197
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A comparison of the molecular structures of the five-co-ordinate bis(imido) and imido alkylidene molybdenum complexes [Mo(NC6H3Pr2i-2,6)(L)(L')]; where L is a tridentate pyridinediolato ligand and L' is either NC6H3Pr2i-2,6 or CHCMe(2)Ph, strongly supports the notion that the nitrogen of the bent imido ligand in the bis(imido) complex is sp(2)-hybridised.
引用
收藏
页码:4197 / 4199
页数:3
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