A STERIC PREFERENCE FOR LINEAR VERSUS BENT IMIDO LIGATION - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF [MO(NAR)2(EDTC)2] (AR = 2,6-IPR2C6H3 EDTC = S2CNET2) CONTAINING 2 LINEAR IMIDO MOIETIES

被引：20

作者：

COFFEY, TA ^{[1
]}

FORSTER, GD ^{[1
]}

HOGARTH, G ^{[1
]}

SELLA, A ^{[1
]}

机构：

[1] UNIV LONDON UNIV COLL,DEPT CHEM,20 GORDON ST,LONDON WC1H 0AJ,ENGLAND

来源：

POLYHEDRON | 1993年 / 12卷 / 22期

关键词：

D O I：

10.1016/S0277-5387(00)80127-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of two equivalents of ArNCO (Ar = 2,6-(1)Pr2C6H3) with [MoO2(edtc)2] affords the bisimido complex [Mo(NAr)2(edtc)2] shown by crystallography to contain two linear imido ligands; this is in contrast to the parent complex [Mo(NPh)2(edtc)2] previously shown to contain both linear and bent imido groups.

引用

页码：2741 / 2743

页数：3

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