Single-walled carbon nanotubes tethered with porphyrins: Synthesis and photophysical properties

被引:141
作者
Li, HP
Martin, RB
Harruff, BA
Carino, RA
Allard, LF
Sun, YP [1 ]
机构
[1] Clemson Univ, Dept Chem, Howard L Hunter Chem Lab, Clemson, SC 29634 USA
[2] Oak Ridge Natl Lab, High Temp Mat Lab, Oak Ridge, TN 37831 USA
关键词
D O I
10.1002/adma.200306288
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis and photophysical properties of single-walled carbon nanotubes (SWNT) tethered with porphyrins was analyzed. The excited-state energy transfer quenching of porphyrin fluorescence by SWNT was found to be dependent on the length of tether. Investigations show that the Raman spectra of the porphyrin-SWNT samples exhibited characteristic peaks after thermal defunctionalization. The results show that the porphyrin-decorated SWNT compete effectively in applications dominated by dye-functionalized nanoparticles.
引用
收藏
页码:896 / 900
页数:5
相关论文
共 40 条
  • [1] Photocurrent generation in multilayer organic-inorganic thin films with cascade energy architectures
    Abdelrazzaq, FB
    Kwong, RC
    Thompson, ME
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (17) : 4796 - 4803
  • [2] Ago H, 1999, ADV MATER, V11, P1281, DOI 10.1002/(SICI)1521-4095(199910)11:15<1281::AID-ADMA1281>3.0.CO
  • [3] 2-6
  • [4] Nanotubes from carbon
    Ajayan, PM
    [J]. CHEMICAL REVIEWS, 1999, 99 (07) : 1787 - 1799
  • [5] AJAYAN PM, 2001, CARBON NANOTUBES SYN, V80
  • [6] Logic circuits with carbon nanotube transistors
    Bachtold, A
    Hadley, P
    Nakanishi, T
    Dekker, C
    [J]. SCIENCE, 2001, 294 (5545) : 1317 - 1320
  • [7] BIRKS JB, 1970, ORGANIC MOL PHOTOPHY
  • [8] Solution properties of single-walled carbon nanotubes
    Chen, J
    Hamon, MA
    Hu, H
    Chen, YS
    Rao, AM
    Eklund, PC
    Haddon, RC
    [J]. SCIENCE, 1998, 282 (5386) : 95 - 98
  • [9] Noncovalent functionalization of carbon nanotubes for highly specific electronic biosensors
    Chen, RJ
    Bangsaruntip, S
    Drouvalakis, KA
    Kam, NWS
    Shim, M
    Li, YM
    Kim, W
    Utz, PJ
    Dai, HJ
    [J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2003, 100 (09) : 4984 - 4989
  • [10] Chemical and biochemical sensing with modified single walled carbon nanotubes
    Davis, JJ
    Coleman, KS
    Azamian, BR
    Bagshaw, CB
    Green, MLH
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (16) : 3732 - 3739