Prospect of hydrogen technology using proton-conducting ceramics

被引:369
作者
Iwahara, H
Asakura, Y
Katahira, K
Tanaka, M
机构
[1] Nagoya Univ, Ctr Integrated Res Sci & Engn, Nagoya 4630034, Japan
[2] Natl Inst Fus Sci, Gifu 5095292, Japan
[3] TYK Co Ltd, Gifu 5078607, Japan
[4] Nagoya Univ, Dept Nucl Engn, Nagoya 4640083, Japan
关键词
proton-conducting ceramic; hydrogen sensor; hydrogen pump; steam electrolyzer; nuclear fusion reactor;
D O I
10.1016/j.ssi.2003.03.001
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This paper reviews possible hydrogen devices using a proton-conducting ceramic and describes the prospect of hydrogen technology utilizing these devices. Solid-state protonic devices can be classified into two categories: the devices utilizing electromotive force (EMF) and the ones utilizing preferential transport of protons. Galvanic cell type hydrogen sensors and fuel cells belong to the former, and hydrogen pump, steam electrolyzer and membrane reactors to the latter. Various kinds of modifications can be derived, in principle, from these devices. In this paper, the working principles of these devices and status of the development are reviewed touching the future prospect of applications. In addition, the recent studies and the possibilities of protonic devices for nuclear fusion process in the future are introduced. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:299 / 310
页数:12
相关论文
共 44 条
[1]   H-2 oxidation at the interface Ni/Sr0.995Ce0.95Y0.05O2.975 [J].
Bonanos, N ;
Mogensen, M .
SOLID STATE IONICS, 1997, 97 (1-4) :483-488
[2]   Oxide-based protonic conductors: point defects and transport properties [J].
Bonanos, N .
SOLID STATE IONICS, 2001, 145 (1-4) :265-274
[3]   ELECTROCATALYTIC NONOXIDATIVE DIMERIZATION OF METHANE OVER AG ELECTRODES [J].
CHIANG, PH ;
ENG, D ;
STOUKIDES, M .
SOLID STATE IONICS, 1993, 61 (1-3) :99-103
[4]  
CHIANG PH, 1993, J CATAL, V139, P63
[5]  
FUKATSU N, 2000, P 26 SEM SSI SOC JAP, P28
[6]   ELECTROCHEMICAL METHANE COUPLING USING PROTONIC CONDUCTORS [J].
HAMAKAWA, S ;
HIBINO, T ;
IWAHARA, H .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1993, 140 (02) :459-462
[7]   ELECTROCHEMICAL HYDROGEN PERMEATION IN A PROTON-HOLE MIXED CONDUCTOR AND ITS APPLICATION TO A MEMBRANE REACTOR [J].
HAMAKAWA, S ;
HIBINO, T ;
IWAHARA, H .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (07) :1720-1725
[8]   Synthesis and hydrogen permeation properties of membranes based on dense SrCe0.95Yb0.05O3-α thin films [J].
Hamakawa, S ;
Li, L ;
Li, A ;
Iglesia, E .
SOLID STATE IONICS, 2002, 148 (1-2) :71-81
[9]   TECHNOLOGICAL CHALLENGES IN THE APPLICATION OF PROTON CONDUCTING CERAMICS [J].
IWAHARA, H .
SOLID STATE IONICS, 1995, 77 :289-298
[10]  
IWAHARA H, 1991, DENKI KAGAKU, V59, P76