Characteristics of pyrolyzed phenol-formaldehyde resin as an anode for lithium-ion batteries

被引：17

作者：

Huang, BY ^{[1
]}

Huang, YZ ^{[1
]}

Wang, ZX ^{[1
]}

Chen, LQ ^{[1
]}

Xue, RJ ^{[1
]}

Wang, FS ^{[1
]}

机构：

[1] CHINESE ACAD SCI,BEIJING 100864,PEOPLES R CHINA

来源：

JOURNAL OF POWER SOURCES | 1996年 / 58卷 / 02期

基金：

中国国家自然科学基金;

关键词：

resins; phenol-formaldehyde; lithium-ion batteries; anodes;

D O I：

10.1016/S0378-7753(96)02373-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Polyacenic semiconductor (PAS) is obtained by pyrolyzing phenol-formaldehyde resin (PFR). The properties of PFR heat-treated at different temperatures are investigated. The lithium intercalation capacity of PAS as a function of heat-treatment temperature (HTT) exhibits a maximum at around 700 degrees C. A knee appears at 700 degrees C, not only in the plot of atomic ratio [H]/[C] versus HTT, but also in the plot of conductivity versus HTT. For PAS with a HTT of 700 degrees C, the maximum in the ratio of the relative intensity of Raman spectra at 1360 cm(-1) corresponds to nanometer graphite, and that at 1580 cm(-1) to graphite. A reasonable explanation of these phenomena is the transformation of nanometer graphite to graphite.

引用

页码：231 / 234

页数：4