Guest exchange in dimeric capsules of a tetraurea calix[4] arene in the solid state

被引：21

作者：

Ziganshin, Marat A.

Yakimova, Ludmila S.

Khayarov, Khasan R.

Gorbatchuk, Valery V.

Vysotsky, Myroslav O.

Boehmer, Volker

机构：

[1] Kazan VI Lenin State Univ, Inst Chem, Kazan 420008, Russia

[2] Johannes Gutenberg Univ Mainz, Fachbereich Chem Pharm & Geowissensch, Abt Lehrant Chem, D-55099 Mainz, Germany

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 37期

关键词：

D O I：

10.1039/b607568a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A solid powder of hydrogen bonded dimers of a tetraurea calix[ 4] arene is able to exchange the encapsulated guest in contact with the vapor of a second guest. The molecules of a guest-free powder obtained from a polar solvent cannot rearrange in the solid phase to form new guest-filled capsules under these conditions.

引用

收藏

页码：3897 / 3899

页数：3

相关论文

共 29 条

[1] Guest exchange in single crystals of van der Waals nanocapsules [J].

Ananchenko, GS ;

Udachin, KA ;

Dubes, A ;

Ripmeester, JA ;

Perrier, T ;

Coleman, AW .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (10) :1585-1588

[2] A new type of material for the recovery of hydrogen from gas mixtures [J].

Atwood, JL ;

Barbour, LJ ;

Jerga, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (22) :2948-2950

[3] Polymorphism of pure p-tert-butylcalix[4]arene:: conclusive identification of the phase obtained by desolvation [J].

Atwood, JL ;

Barbour, LJ ;

Jerga, A .

CHEMICAL COMMUNICATIONS, 2002, (24) :2952-2953

[4] Self-recognition, structure, stability, and guest affinity of pyrogallol[4]arene and resorcin[4]arene capsules in solution [J].

Avram, L ;

Cohen, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (37) :11556-11563

[5] Crystal structure and thermodynamics of reversible molecular capsules [J].

Chapman, RG ;

Olovsson, G ;

Trotter, J ;

Sherman, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (25) :6252-6260

[6] Guest encapsulation in a water-soluble molecular capsule based on ionic interactions [J].

Corbellini, F ;

Di Costanzo, L ;

Crego-Calama, M ;

Geremia, S ;

Reinhoudt, DN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (33) :9946-9947

[7] Resorcinarenes with 2-benzimidazolone bridges: Self-aggregation, self-assembled dimeric capsules, and guest encapsulation [J].

Ebbing, MHK ;

Villa, MJ ;

Valpuesta, JM ;

Prados, P ;

de Mendoza, J .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2002, 99 (08) :4962-4966

[8]

Fox OD, 2000, ANGEW CHEM INT EDIT, V39, P136

[9] Thermodynamic comparison of molecular recognition of vaporous guests by solid calixarene and diol hosts [J].

Gorbatchuk, VV ;

Tsifarkin, AG ;

Antipin, IS ;

Solomonov, BN ;

Konovalov, AI ;

Seidel, J ;

Baitalov, F .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 2000, (11) :2287-2294

[10] Nonlinear structure-affinity relationships for vapor guest inclusion by solid calixarenes [J].

Gorbatchuk, VV ;

Tsifarkin, AG ;

Antipin, IS ;

Solomonov, BN ;

Konovalov, AI ;

Lhotak, P ;

Stibor, I .

JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (23) :5845-5851