Guest exchange in single crystals of van der Waals nanocapsules

被引:57
作者
Ananchenko, GS
Udachin, KA
Dubes, A
Ripmeester, JA
Perrier, T
Coleman, AW
机构
[1] Natl Res Council Canada, Steacie Inst Mol Sci, Ottawa, ON K1A 0R6, Canada
[2] Inst Chim & Biol Prot, F-69367 Lyon 07, France
关键词
calixarenes; crystal growth; host-guest systems; self-assembly; supramolecular chemistry;
D O I
10.1002/anie.200503553
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Currency exchange! Amphiphilic parahexanoylcalix[4]arenes can form hydrophobic van der Waals nanocapsules (see picture) which are flexible enough to allow efficient guest exchange without destroying the crystal lattice. Purple: C (dibenzylketone), green: Cl(CHCl3), red: O, white: H. (Figure Presented) © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:1585 / 1588
页数:4
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