Synthesis of nitrogen-doped fullerenes by vaporization of graphite and characterization using NEXAFS and temperature programmed combustion

被引：12

作者：

Jia, YF ^{[1
]}

Zhu, Q ^{[1
]}

Thomas, KM ^{[1
]}

机构：

[1] Newcastle Univ, Dept Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

CHEMICAL PHYSICS LETTERS | 2002年 / 364卷 / 1-2期

关键词：

D O I：

10.1016/S0009-2614(02)01328-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nitrogen-doped fullerenes were synthesized by vaporization of graphite under the atmosphere of nitrogen and helium mixture. The types of nitrogen incorporated into the fullerenes were studied by near edge X-ray absorption fine structure and temperature programmed combustion. The results show that, in addition to the substitution of carbon atoms of the fullerene cages, nitrogen was also introduced into the fullerenes as HCN and CN which are probably chemically adsorbed on the cages. (C) 2002 Published by Elsevier Science B.V.

引用

页码：171 / 175

页数：5

共 18 条

[1] Chemisorption of azafullerene on silicon:: isolating C59N monomers [J].

Butcher, MJ ;

Jones, FH ;

Cotier, BN ;

Taylor, MDR ;

Moriarty, P ;

Beton, PH ;

Prassides, K ;

Tagmatarchis, N ;

Comicioli, C ;

Ottaviani, C ;

Crotti, C .

MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2000, 74 (1-3) :202-205

[2] C59N monomers:: Stabilization through immobilization [J].

Butcher, MJ ;

Jones, FH ;

Beton, PH ;

Moriarty, P ;

Cotier, BN ;

Upward, MD ;

Prassides, K ;

Kordatos, K ;

Tagmatarchis, N ;

Wudl, F ;

Dhanak, V ;

Johal, TK ;

Crotti, C ;

Comicioli, C ;

Ottaviani, C .

PHYSICAL REVIEW LETTERS, 1999, 83 (17) :3478-3481

[3] K-SHELL PHOTOABSORPTION OF THE N2 MOLECULE [J].

CHEN, CT ;

MA, Y ;

SETTE, F .

PHYSICAL REVIEW A, 1989, 40 (11) :6737-6740

[4] Formation of nitrogen doped carbon during arc-discharge of carbon rods in the presence of pyrrole [J].

Glenis, S ;

Nelson, AJ ;

Labes, MM .

JOURNAL OF APPLIED PHYSICS, 1996, 80 (09) :5404-5407

[5] INNER SHELL ELECTRON-ENERGY LOSS STUDIES OF HCN AND C2N2 [J].

HITCHCOCK, AP ;

BRION, CE .

CHEMICAL PHYSICS, 1979, 37 (03) :319-331

[6] ISOLATION OF THE HETEROFULLERENE C59N AS ITS DIMER (C59N)(2) [J].

HUMMELEN, JC ;

KNIGHT, B ;

PAVLOVICH, J ;

GONZALEZ, R ;

WUDL, F .

SCIENCE, 1995, 269 (5230) :1554-1556

[7] CYANODIHYDROFULLERENES AND DICYANODIHYDROFULLERENE - THE FIRST POLAR SOLID BASED ON C-60 [J].

KESHAVARZ, M ;

KNIGHT, B ;

SRDANOV, G ;

WUDL, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (45) :11371-11372

[8] Synthesis of hydroazafullerene C59HN, the parent hydroheterofullerene [J].

KeshavarzK, M ;

Gonzalez, R ;

Hicks, RG ;

Srdanov, G ;

Srdanov, VI ;

Collins, TG ;

Hummelen, JC ;

BellaviaLund, C ;

Pavlovich, J ;

Wudl, F ;

Holczer, K .

NATURE, 1996, 383 (6596) :147-150

[9] SOLID C-60 - A NEW FORM OF CARBON [J].

KRATSCHMER, W ;

LAMB, LD ;

FOSTIROPOULOS, K ;

HUFFMAN, DR .

NATURE, 1990, 347 (6291) :354-358

[10]

Krause M, 2001, J PHYS CHEM B, V105, P11964, DOI [10.1021/jp012186+, 10.1021/jp012186]

← 1 2 →