Ni-catalyzed activation of α-chloroesters:: a simple method for the synthesis of α-arylesters and β-hydroxyesters

被引：97

作者：

Durandetti, Muriel ^{[1
]}

Gosmini, Corinne ^{[1
]}

Perichon, Jacques ^{[1
]}

机构：

[1] Univ Paris 12, CNRS, UMR 7582, Lab Electrochim Catalyse & Synthese Organ, F-94320 Thiais, France

来源：

TETRAHEDRON | 2007年 / 63卷 / 05期

关键词：

D O I：

10.1016/j.tet.2006.11.055

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Coupling reactions of alpha-chloroesters with aryl halides (alpha-arylation) or carbonyl compounds (Reformatsky) using nickel catalyst allow, under mild conditions, the preparation of various functionalized aryl propionic acid derivatives or beta-hydroxyesters. In the synthesis of aryl propionic acid derivatives, the process is efficient with aryl halides bearing either electron-withdrawing or electron-donating groups. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：1146 / 1153

页数：8

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