Dynamic motion of building blocks in porous coordination polymers

被引：214

作者：

Horike, Satoshi

Matsuda, Ryotaro

Tanaka, Daisuke

Matsubara, Seijiro

Mizuno, Motohiro

Endo, Kazunaka

Kitagawa, Susumu ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan

[2] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Nishikyo Ku, Kyoto 6158510, Japan

[3] Kanazawa Univ, Grad Sch Nat Sci & Technol, Dept Chem, Kanazawa, Ishikawa 9201192, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 43期

关键词：

cadmium; coordination polymers; metal-organic frameworks; molecular dynamics; NMR spectroscopy;

D O I：

10.1002/anie.200603196

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Controlling guests: Porous coordination polymers containing mobile organic groups, such as naphthalene rings (see picture), are synthesized, and their rotational motion is characterized by solid-state 2H NMR spectroscopy. The rotation of the groups can be switched off (blue) by guest (blue spheres) adsorption and switched on (yellow) again by guest desorption. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：7226 / 7230

页数：5

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