Copper-catalyzed Suzuki cross-coupling using mixed nanocluster catalysts

被引：265

作者：

Thathagar, MB ^{[1
]}

Beckers, J ^{[1
]}

Rothenberg, G ^{[1
]}

机构：

[1] Univ Amsterdam, Dept Chem Engn, NL-1018 WV Amsterdam, Netherlands

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 40期

关键词：

D O I：

10.1021/ja027716+

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A small library of copper and noble metal nanoclusters is designed and synthesized. These clusters are tested as catalysts in the Suzuki cross-coupling of various aryl halides with phenylboronic acid. It is found that copper and copper/noble metal combination nanoclusters are active catalysts for this reaction, the most active being the combined copper/palladium clusters. Iodo-, bromo-, and chloroarenes can be used. In the case of p-nitrobromobenzene, a one-pot cross-coupling and selective hydrogenation is achieved. Copyright © 2002 American Chemical Society.

引用

页码：11858 / 11859

页数：2

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