Synthesis and spectroscopic characterization of single-wall carbon nanotubes wrapped by glycoconjugate polymer with bioactive sugars

被引:25
作者
Dohi, Hirofumi
Kikuchi, Satoshi
Kuwahara, Shota
Sugai, Toshiki
Shinohara, Hisanori [1 ]
机构
[1] Nagoya Univ, Dept Chem, Nagoya, Aichi 4648602, Japan
[2] Nagoya Univ, Inst Adv Res, Nagoya, Aichi 4648602, Japan
基金
日本学术振兴会;
关键词
CARBOHYDRATE-PROTEIN INTERACTIONS; MULTIVALENT LIGANDS; POLYSTYRENE; FUNCTIONALIZATION; OLIGOSACCHARIDES; FLUORESCENCE; DISPERSION;
D O I
10.1016/j.cplett.2006.06.053
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel multivalent carbohydrate-CNT hybrid has been synthesized from SWNT and glycoconjugate polymer, carrying carbohydrate as pendant groups at side chain. Dispersion of SWNT in aqueous solution by using glycoconjugate polymer is achieved by sonication and ultracentrifugation. The multivalent carbohydrate-CNT hybrid is revealed to be photoluminescence active by near-infrared fluorescence spectroscopy. AFM measurements of the hybrid support not only the wrapping of SWNT by glycoconjugate polymer but also successful carbohydrate attachment of individual SWNT. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:98 / 101
页数:4
相关论文
共 32 条
[1]   Structure-assigned optical spectra of single-walled carbon nanotubes [J].
Bachilo, SM ;
Strano, MS ;
Kittrell, C ;
Hauge, RH ;
Smalley, RE ;
Weisman, RB .
SCIENCE, 2002, 298 (5602) :2361-2366
[2]   Near-infrared optical sensors based on single-walled carbon nanotubes [J].
Barone, PW ;
Baik, S ;
Heller, DA ;
Strano, MS .
NATURE MATERIALS, 2005, 4 (01) :86-U16
[3]   Biomimetic engineering of carbon nanotubes by using cell surface mucin mimics [J].
Chen, X ;
Lee, GS ;
Zettl, A ;
Bertozzi, CR .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (45) :6111-6116
[4]   Optical characterization of DNA-wrapped carbon nanotube hybrids [J].
Chou, SG ;
Ribeiro, HB ;
Barros, EB ;
Santos, AP ;
Nezich, D ;
Samsonidze, GG ;
Fantini, C ;
Pimenta, MA ;
Jorio, A ;
Plentz, F ;
Dresselhaus, MS ;
Dresselhaus, G ;
Saito, R ;
Zheng, M ;
Onoa, GB ;
Semke, ED ;
Swan, AK ;
Ünlü, MS ;
Goldberg, BB .
CHEMICAL PHYSICS LETTERS, 2004, 397 (4-6) :296-301
[5]   Synthesis of an artificial glycoconjugate polymer carrying Pk-antigenic trisaccharide and its potent neutralization activity against Shiga-like toxin [J].
Dohi, H ;
Nishida, Y ;
Mizuno, M ;
Shinkai, M ;
Kobayashi, T ;
Takeda, T ;
Uzawa, H ;
Kobayashi, K .
BIOORGANIC & MEDICINAL CHEMISTRY, 1999, 7 (09) :2053-2062
[6]   Single-walled carbon nanotubes displaying multivalent ligands for capturing pathogens [J].
Gu, LR ;
Elkin, T ;
Jiang, XP ;
Li, HP ;
Lin, Y ;
Qu, LW ;
Tzeng, TRJ ;
Joseph, R ;
Sun, YP .
CHEMICAL COMMUNICATIONS, 2005, (07) :874-876
[7]   First comparative emission assay of single-wall carbon nanotubes - solutions and dispersions [J].
Guldi, DM ;
Holzinger, M ;
Hirsch, A ;
Georgakilas, V ;
Prato, M .
CHEMICAL COMMUNICATIONS, 2003, (10) :1130-1131
[8]   Single-walled carbon nanotubes acquire a specific lectin-affinity through supramolecular wrapping with lactose-appended schizophyllan [J].
Hasegawa, T ;
Fujisawa, T ;
Numata, M ;
Umeda, M ;
Matsumoto, T ;
Kimura, T ;
Okumura, S ;
Sakurai, K ;
Shinkai, S .
CHEMICAL COMMUNICATIONS, 2004, (19) :2150-2151
[9]  
Hirsch A, 2002, ANGEW CHEM INT EDIT, V41, P1853, DOI 10.1002/1521-3773(20020603)41:11<1853::AID-ANIE1853>3.0.CO
[10]  
2-N