scanning tunneling microscopy;
surface relaxation and reconstruction;
alkynes;
carbon;
silicon;
D O I:
10.1016/S0039-6028(02)02056-3
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
We report the formation of atomically flat Si(0 0 1) surfaces with C incorporation using thermal dissociation Of C2H2 molecules. The resulting surface phases are investigated by scanning tunneling microscopy and found to contain C atoms as much as 0.2 monolayer (ML) without roughening. At low C concentrations, C-induced vacancy line defects are generated on the surface, forming a 2 x n superstructure. As the C concentration increases, a new phase with a c(4 x 4) structure starts to appear and coexists with the 2 x n phase, eventually covering the whole surface at about 0.2 ML. The C atoms in the 2 x n superstructure are thought to occupy substitutional sites in a subsurface layer and constitute a delta-like distribution. (C) 2002 Elsevier Science B.V. All rights reserved.