Asymmetric dihydroxylation and one-pot epoxidation routes to (+)- and (-)-posticlure:: a novel trans-epoxide as a sex pheromone component of Orgyia postica (Walker)

被引：20

作者：

Fernandes, RA ^{[1
]}

Kumar, P ^{[1
]}

机构：

[1] Natl Chem Lab, Div Organ Chem Technol, Pune 411008, Maharashtra, India

来源：

TETRAHEDRON | 2002年 / 58卷 / 33期

关键词：

asymmetric synthesis; dihydroxylation; one-pot epoxidation; pheromone; posticlure;

D O I：

10.1016/S0040-4020(02)00685-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A highly enantioselective synthesis of (+)- and (-)-posticlure has been achieved. The synthesis features the Sharpless asymmetric dihydroxylation and one-pot epoxidation as the key steps. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：6685 / 6690

页数：6

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