Piperazinediium bis(pyridine-2,6-dicarboxylato)-manganate(II) hexahydrate

被引:18
作者
Aghabozorg, Hossein
Ghasemikhah, Pouya
Soleimannejad, Janet
Ghadermazi, Mohammad
Gharamaleki, Jafar Attar
机构
[1] Teacher Training Univ, Dept Chem, Tehran 15614, Iran
[2] Bar Ilan Univ, Fac Sci, Dept Chem, IL-52100 Ramat Gan, Israel
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2006年 / 62卷
关键词
D O I
10.1107/S1600536806032521
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The reaction of manganese(II) nitrate with the proton-transfer compound piperazinediium pyridine- 2,6-dicarboxylate, or (pipzH(2))(pydc), in aqueous solution leads to the formation of the title compound, (C4H12N2)[Mn(C7H3NO4)(2)]center dot 6H(2)O. The anion is a six-coordinate complex with a distorted octahedral geometry around the central atom. In the crystal structure, intra- and intermolecular O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds connect the various components into a supramolecular structure.
引用
收藏
页码:M2266 / M2268
页数:3
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