Fungal deracemization of benzoin

被引：33

作者：

Demir, AS ^{[1
]}

Hamamci, H

Sesenoglu, O

Neslihanoglu, R

Asikoglu, B

Capanoglu, D

机构：

[1] Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey

[2] Middle E Tech Univ, Dept Biotechnol, TR-06531 Ankara, Turkey

[3] Middle E Tech Univ, Dept Food Engn, TR-06531 Ankara, Turkey

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 36期

关键词：

fungi; deracemization; hydroxyketones; benzoin;

D O I：

10.1016/S0040-4039(02)01362-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An enzyme system of Rhizopus oryzae (ATCC 9363) catalyzes the inversion of the chirality of benzoin via a deracemization reaction and, depending on the pH of the medium, both enantiomers of benzoin are obtained in good yield and high ee starting from rac-benzoin. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：6447 / 6449

页数：3