Tetrahedra, super-tetrahedra, bipyramids, boxes and more: Polymetallic clusters of benzotriazole

被引：23

作者：

Collison, David

McInnes, Eric J. L.

Brechin, Euan K.

机构：

[1] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

[2] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2006年 / 14期

关键词：

benzotriazole; clusters; transition metals; large spin ground states; single-molecule magnets;

D O I：

10.1002/ejic.200600206

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The syntheses, structures and magnetic properties of a host of polymetallic 3d transition-metal clusters made with the pro-ligand benzotriazole (BtaH) and its analogues are reported. These range from a family of tetradecametallic clusters with spin ground states as large as S approximate to 25, to decametallic vanadium "boxes", to iron and manganese tetra- and super-tetrahedra, to hexaicosametallic manganese single-molecule magnets. (c) Wiley-VCH Verlag GmbH & Co.

引用

页码：2725 / 2733

页数：9

共 48 条

[1] BENZOTRIAZOLATE-MEDIATED ASSEMBLY OF THE DISCRETE ASYMMETRIC PENTANUCLEAR NICKEL-COMPLEX [NI-5(OH)(BTA)(5)(ACAC)(4)(H2O)(4)] (HBTA=BENZOTRIAZOLE, HACAC=PENTANE-2,4-DIONE) [J].