Simple one-pot transformations of toluene-p-sulfonates of 2,3-epoxy alcohols into allylic alcohols

被引：13

作者：

Fujii, N

Habashita, H

Akaji, M

Nakai, K

Ibuka, T

Fujiwara, M

Tamamura, H

Yamamoto, Y

机构：

[1] KYOTO UNIV,FAC PHARMACEUT SCI,SAKYO KU,KYOTO 60601,JAPAN

[2] TOHOKU UNIV,DEPT CHEM,SENDAI,MIYAGI 980,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1996年 / 09期

关键词：

D O I：

10.1039/p19960000865

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple synthetic method for the preparation of scalemic allylic alcohols from toluene-p-sulfonates of scalemic 2,3-epoxy alcohols is reported. Satisfactory yields are obtained by treatment of toluene-p-sulfonates of 2,3-epoxy alcohols with potassium iodide followed by triphenylphosphine and iodine in a one-pot synthesis.

引用

收藏

页码：865 / 866

页数：2

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