Synthesis and study of Janus bis(carbene)s and their transition-metal complexes

被引：171

作者：

Khramov, Dimitri M. ^{[1
]}

Boydston, Andrew J. ^{[1
]}

Bielawski, Christopher W. ^{[1
]}

机构：

[1] Univ Texas, Dept Chem & Biochem, Austin, TX 78712 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 37期

关键词：

azolium salts; carbene ligands; heterometallic complexes; organic-inorganic hybrid composites; transition metals;

D O I：

10.1002/anie.200601583

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Deuces wild: From catalysis through materials science to biology, N-heterocyclic carbenes (NHCs) can truly be regarded as a wild card of ligands. A new series of two-faced" (Janus-type) ligands composed of two linearly opposed NHCs fused to an arene linker has been synthesized and can be used to prepare discrete bimetallic complexes. (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA."

引用

页码：6186 / 6189

页数：4

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