Electrografting of 3-methyl thiophene onto carbon fiber:: characterizatioi and carbazole random copolymer by FTIR-ATR, SEM, EDX

被引：39

作者：

Saraç, AS ^{[1
]}

Springer, J ^{[1
]}

机构：

[1] Tech Univ Berlin, Inst Tech Chem, Fachgebiet Makromol Chem, D-10623 Berlin, Germany

来源：

SURFACE & COATINGS TECHNOLOGY | 2002年 / 160卷 / 2-3期

关键词：

electrografting; carbon fiber; electrocopolymerization; carbazole; 3-methylthiophene; scanning electron microscopy;

D O I：

10.1016/S0257-8972(02)00388-2

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Electrografting of poly(3-methylthiophene-co-carbazole) onto high tenacity (TENAX HTA 5000) carbon fiber was carried out under preparative constant-current electrolysis conditions by electropolymerizing in non-aqueous media. The surface morphology of the electrografted carbon fibers was determined by scanning electron microscopy (SEM). For characterization of the chemical composition of the random copolymer, FTIR reflectance measurements (FTIR-ATR) were performed. The efficiency of the electrocopolymerization on carbon fiber surfaces under preparative constant-current electrolysis conditions as a function of the experimental conditions was evaluated (effect on thickness and morphology). (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：227 / 238

页数：12

共 30 条

[11]

KOSSMEHL GA, 1986, HDB CONDUCTING POLYM, P351

[12] Electrografting of thiophene, carbazole, pyrrole and their copolymers onto carbon fibers:: electrokinetic measurements, surface composition and morphology [J].

Kumru, ME ;

Springer, J ;

Saraç, AS ;

Bismarck, A .

SYNTHETIC METALS, 2001, 123 (03) :391-402

[13] In situ spectroelectrochemical characterization of poly(3,4-ethylenedioxythiophene) [J].

Kvarnström, C ;

Neugebauer, H ;

Blomquist, S ;

Ahonen, HJ ;

Kankare, J ;

Ivaska, A .

ELECTROCHIMICA ACTA, 1999, 44 (16) :2739-2750

[14] SPECTROSCOPIC PROPERTIES OF POLY(3-ALKYLTHIOPHENES) AND THEIR HEAD-TO-HEAD, TAIL-TO-TAIL COUPLED ANALOGS POLY(4,4'-DIALKYL-2,2'-BITHIOPHENES) [J].

LOUARN, G ;

KRUSZKA, J ;

LEFRANT, S ;

ZAGORSKA, M ;

KULSZEWICZBAYER, I ;

PRON, A .

SYNTHETIC METALS, 1993, 61 (03) :233-238

[15] EXPERIMENTAL AND THEORETICAL-STUDY OF VIBRATIONAL PROPERTIES OF POLYTHIOPHENE, POLYMETHYLTHIOPHENE AND POLYOCTYLTHIOPHENE [J].

LOUARN, G ;

MEVELLEC, JY ;

BUISSON, JP ;

LEFRANT, S .

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1992, 89 (05) :987-995

[16]

MCCLAIN MD, 1996, POLYM SCI TECHNOLOGY

[17]

REDDINGER JL, 1996, CHEM COMMUN, V15, P1777

[18]

RENEE E, 1993, ADV MATER, V5, P547

[19] CONJUGATED POLY(THIOPHENES) - SYNTHESIS, FUNCTIONALIZATION, AND APPLICATIONS [J].

RONCALI, J .

CHEMICAL REVIEWS, 1992, 92 (04) :711-738

[20] Electrografting of poly(carbazole-co-acrylamide) onto several carbon fibers -: Electrokinetic and surface properties [J].

Saraç, AS ;

Bismarck, A ;

Kumru, ME ;

Springer, J .

SYNTHETIC METALS, 2001, 123 (03) :411-423

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