Electrochemical studies of capacitance in cerium oxide thin films and its relationship to anionic and electronic defect densities

被引：97

作者：

Chueh, William C. ^{[1
]}

Haile, Sossina M. ^{[1
]}

机构：

[1] CALTECH, Dept Mat Sci, Pasadena, CA 91125 USA

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2009年 / 11卷 / 37期

基金：

美国国家科学基金会;

关键词：

CHEMICAL CAPACITANCE; MIXED CONDUCTORS; SINGLE-CRYSTALS; IMPEDANCE; TRANSPORT; NONSTOICHIOMETRY; SEMICONDUCTORS; MODEL; LA0.6SR0.4COO3-DELTA; BEHAVIOR;

D O I：

10.1039/b910903j

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Small polaron carrier density in epitaxial, doped CeO2 thin films under low oxygen partial pressure was determined from electrochemically-measured capacitance after accounting for interfacial effects and shown to agree well with bulk values.

引用

收藏

页码：8144 / 8148

页数：5

相关论文

共 38 条

[1] Factors governing oxygen reduction in solid oxide fuel cell cathodes [J].

Adler, SB .

CHEMICAL REVIEWS, 2004, 104 (10) :4791-4843

[2] FERROELECTRIC FIELD-EFFECT IN EPITAXIAL THIN-FILM OXIDE SRCUO2/PB(ZR0.52TI0.48)O-3 HETEROSTRUCTURES [J].

AHN, CH ;

TRISCONE, JM ;

ARCHIBALD, N ;

DECROUX, M ;

HAMMOND, RH ;

GEBALLE, TH ;

FISCHER, O ;

BEASLEY, MR .

SCIENCE, 1995, 269 (5222) :373-376

[3] Thin-film lithium and lithium-ion batteries [J].

Bates, JB ;

Dudney, NJ ;

Neudecker, B ;

Ueda, A ;

Evans, CD .

SOLID STATE IONICS, 2000, 135 (1-4) :33-45

[4] Impedance spectroscopic study on well-defined (La,Sr)(Co,Fe)O3-δ model electrodes [J].

Baumann, Frank S. ;

Fleig, Juergen ;

Habermeier, Hanns-Ulrich ;

Maier, Joachim .

SOLID STATE IONICS, 2006, 177 (11-12) :1071-1081

[5] Defect equilibria and chemical expansion in non-stoichiometric undoped and gadolinium-doped cerium oxide [J].

Bishop, S. R. ;

Duncan, K. L. ;

Wachsman, E. D. .

ELECTROCHIMICA ACTA, 2009, 54 (05) :1436-1443

[6] Chemical capacitance of nanostructured semiconductors: its origin and significance for nanocomposite solar cells [J].

Bisquert, J .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2003, 5 (24) :5360-5364

[7] A review of recent results on electrochemical determination of the density of electronic states of nanostructured metal-oxide semiconductors and organic hole conductors [J].

Bisquert, Juan ;

Fabregat-Santiago, Francisco ;

Mora-Sero, Ivan ;

Garcia-Belmonte, Germa ;

Barea, Eva M. ;

Palomares, Emilio .

INORGANICA CHIMICA ACTA, 2008, 361 (03) :684-698

[8] OXYGEN-DEFICIENT BARIUM LEAD-OXIDE PEROVSKITES [J].

CAVA, RJ ;

TAKAGI, H ;

KRAJEWSKI, JJ ;

PECK, WF ;

HWANG, HY .

PHYSICAL REVIEW B, 1993, 47 (17) :11525-11528

[9] Nonstoichiometry and Electrical Conductivity of Nanocrystalline CeO\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document} $${2 - x} $$ \end{document} [J].

E B Lavik ;

I Kosacki ;

H L Tuller ;

Y-M Chiang ;

J Y Ying .

Journal of Electroceramics, 1997, 1 (1) :7-14

[10] Structure and thermal stability of ceria films supported on YSZ(100) and α-Al2O3(0001) [J].

Costa-Nunes, O ;

Ferrizz, RM ;

Gorte, RJ ;

Vohs, JM .

SURFACE SCIENCE, 2005, 592 (1-3) :8-17

← 1 2 3 4 →