Soft Poly(dimethylsiloxane) Elastomers from Architecture-Driven Entanglement Free Design

被引：223

作者：

Cai, Li-Heng ^{[1
]}

Kodger, Thomas E. ^{[1
]}

Guerra, Rodrigo E. ^{[1
]}

Pegoraro, Adrian F. ^{[1
]}

Rubinstein, Michael ^{[2
]}

Weitz, David A. ^{[1
]}

机构：

[1] Harvard Univ, John A Paulson Sch Engn & Appl Sci, Cambridge, MA 02138 USA

[2] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA

来源：

ADVANCED MATERIALS | 2015年 / 27卷 / 35期

基金：

美国国家科学基金会;

关键词：

bottlebrush; elastomers; nonsticky; poly(dimethylsiloxane); soft; solvent free; MOLECULAR BRUSHES; MATRIX STIFFNESS; SUBSTRATE; NETWORKS; POLYDIMETHYLSILOXANE; PHENOTYPE; MECHANICS; IMPACT;

D O I：

10.1002/adma.201502771

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Soft, solvent-free poly(dimethylsiloxane) elastomers are fabricated by a one-step process via crosslinking bottlebrush polymers. The bottlebrush architecture prevents the formation of entanglements, resulting in elastomers with precisely controllable low moduli from 1 to 100 kPa, below the lower limit of traditional elastomers; moreover, the solvent-free nature enables their negligible adhesiveness compared to commercially available silicone products of similar stiffness. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5132 / 5140

页数：9

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