NHC-Pd(II) complex-Cu(I) co-catalyzed homocoupling reaction of terminal alkynes

被引：64

作者：

Shi, Min ^{[1
]}

Qian, Heng-xin ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2006年 / 20卷 / 11期

关键词：

trans-cyclohexane-1,2-diamine; terminal alkynes; homocoupling reaction; 1,4-disubstituted 1,3-diynes;

D O I：

10.1002/aoc.1139

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Two NHC-Pd(II) complexes synthesized from traps-cyclohexane-1,2-diamine were fairly effective in the NHC-Pd(II) complex/Cu co-catalyzed terminal alkyne homocoupling reaction to give the corresponding symmetrical 1,4-disubstituted 1,3-diynes in good yields under mild conditions. Copyright (c) 2006 John Wiley & Sons, Ltd.

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页码：771 / 774

页数：4

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