Scanning tunneling microscopy study on the initial adsorption behavior of C-60 molecules on a reconstructed Au(111)-(23x root 3) surface at various temperatures

被引:24
作者
Fujita, D [1 ]
Yakabe, T [1 ]
Nejoh, H [1 ]
Sato, T [1 ]
Iwatsuki, M [1 ]
机构
[1] JEOL LTD,AKISHIMA,TOKYO 196,JAPAN
关键词
carbon; chemisorption; fullerenes; gold; growth; low index single crystal surfaces; scanning tunneling microscopy; surface relaxation and reconstruction;
D O I
10.1016/0039-6028(96)00786-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We have clarified the behavior of initial stage adsorption of C-60 molecules on a reconstructed Au(111)-(23 x root 3) surface at the three temperatures (295, similar to 80 and similar to 30 K) using low-temperature scanning tunneling microscopy. At room temperature, C-60 molecules were found to adsorb only at the step edges and form one-dimensional C-60 nano structures. At similar to 80 K, C-60 molecules were found to adsorb on terraces, but were not stable. The nucleation and growth of two-dimensional C-60 clusters from the one-dimensional C-60 nuclei at step edges were clarified at this temperature. At similar to 30 K, C-60 molecules were found to be trapped, especially at the elbow positions of the herringbone structure of the Au(111) reconstructed surface, which have dislocations and protruded atoms.
引用
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页码:93 / 98
页数:6
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