The crystal structure of the title compound, benzamide-2,3,4,5,6-pentafluorobenzoic acid (2/1), 2C(7)H(7)NO center dot C7HF5O2, consists of centrosymmetric hexameric supermolecules composed of four amide and two carboxylic acid molecules connected via O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds. No phenyl-perfluorophenyl pi-pi stacking interactions are observed in this cocrystal.