[(NH3CH2CH2CH2NH2CH2)2]0.5[Sb7S11]:: A new two-dimensional antimony sulfide with antimony-antimony bonding

被引：49

作者：

Powell, AV ^{[1
]}

Boissière, S

Chippindale, AM

机构：

[1] Heriot Watt Univ, Dept Chem, Edinburgh EH14 4AS, Midlothian, Scotland

[2] Univ Oxford, Chem Crystallog Lab, Oxford OX1 3PD, England

来源：

CHEMISTRY OF MATERIALS | 2000年 / 12卷 / 01期

关键词：

D O I：

10.1021/cm990526m

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new two-dimensional antimony sulfide has been synthesized under hydrothermal conditions in the presence of N,N'-bis(3-aminopropyl)ethylenediamine and characterized by single-crystal X-ray diffraction, thermogravimetry and elemental analysis. The product [C-8- N4H26](0.5)[Sb7S11] (M-r = 1294.07) crystallizes in the triclinic space group, P (1) over bar, with alpha = 5.9550(3)Angstrom b = 14.567(1)Angstrom, c=15.093(1)Angstrom, alpha = 68.448(4)degrees, beta = 863.044(6)degrees, gamma = 82.280(6)degrees, V=1206 Angstrom(3), and Z = 2. The structure consists of infinite chains of formula Sb7S112- linked through antimony-antimony bonds (2.921(2)Angstrom) into two-dimensional slabs of approximate thickness 2.6 Angstrom. These slabs contain pores of dimensions ca. 17.5 x 5.2 Angstrom, which are aligned along the [100] direction. N,N'-Bis(3-aminopropyl)ethylenediamine cations reside between the slabs to which they are hydrogen bonded.

引用

页码：182 / 187

页数：6

共 41 条

[1] SIR92 - a program for automatic solution of crystal structures by direct methods [J].

ALTOMARE, A ;

CASCARANO, G ;

GIACOVAZZO, G ;

GUAGLIARDI, A ;

BURLA, MC ;

POLIDORI, G ;

CAMALLI, M .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1994, 27 :435-435

[2]

Barrer R.M., 1978, ZEOLITES CLAY MINERA

[3] CRYSTAL STRUCTURE OF ANTIMONY AT 4.2, 78 AND 298 DEGREES K [J].

BARRETT, CS ;

CUCKA, P ;

HAEFNER, K .

ACTA CRYSTALLOGRAPHICA, 1963, 16 (06) :451-&

[4] REFINEMENT OF CRYSTAL-STRUCTURE OF STIBNITE, SB2S3 [J].

BAYLISS, P ;

NOWACKI, W .

ZEITSCHRIFT FUR KRISTALLOGRAPHIE KRISTALLGEOMETRIE KRISTALLPHYSIK KRISTALLCHEMIE, 1972, 135 (3-4) :308-&

[5]

BEDARD RL, 1989, ZEOLITES FACTS FIGUR

[6] Hydrothermal synthesis and crystal structure of the new manganese(II) thioantimonate(III), Mn(en)(3)Sb4S7 [J].

Bensch, W ;

Schur, M .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1997, 52 (03) :405-409

[7] Dimetal linked open frameworks: [(CH3)(4)N](2)(Ag-2,Cu-2)Ge4S10 [J].

Bowes, CL ;

Huynh, WU ;

Kirkby, SJ ;

Malek, A ;

Ozin, GA ;

Petrov, S ;

Twardowski, M ;

Young, D ;

Bedard, RL ;

Broach, R .

CHEMISTRY OF MATERIALS, 1996, 8 (08) :2147-2152

[8] BOND-VALENCE PARAMETERS FOR SOLIDS [J].

BRESE, NE ;

OKEEFFE, M .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1991, 47 :192-197

[9] A novel 3-dimensional open framework sulfide based upon the [In10S20]10- supertetrahedron:: DMA-InS-SB1 [J].

Cahill, CL ;

Ko, YH ;

Parise, JB .

CHEMISTRY OF MATERIALS, 1998, 10 (01) :19-21

[10] A novel layered indium sulfide material consisting of corner and edge shared InS4 tetrahedra:: synthesis and structural characterization Of DPA-InS-SB3 [J].

Cahill, CL ;

Gugliotta, B ;

Parise, JB .

CHEMICAL COMMUNICATIONS, 1998, (16) :1715-1716

← 1 2 3 4 5 →