TerpyridineCuII polycarboxylate crystal reorganization to one- and two-dimensional nanostructures:: Crystal disassembly and reassembly

被引:25
作者
Wang, Pingshan
Moorefield, Charles N.
Panzner, Matthew
Newkome, George R. [1 ]
机构
[1] Univ Akron, Dept Polymer Sci, Akron, OH 44325 USA
[2] Univ Akron, Dept Chem, Akron, OH 44325 USA
[3] Univ Akron, Maurice Morton Inst Polymer Sci, Akron, OH 44325 USA
关键词
D O I
10.1021/cg060086t
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Treatment of poly( terpyridineCu(II)-3,5-pyridinedicarboxylate) with [Cu(MeCN)(4)(PF6)] under aqueous basic conditions afforded a new one-dimensional comblike structure with no added Cu; whereas under neutral conditions, a two-dimensional gridlike architecture was formed with newly incorporated metal.
引用
收藏
页码:1563 / 1565
页数:3
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