Solution mediated synthesis and structure of a three-dimensional zinc arsenate, [NH3(CH2)3NH2(CH2)2 NH3][Zn4(AsO4)3(HAsO4)]•H2O, with intersecting helical channels

被引：21

作者：

Chakrabarti, S ^{[1
]}

Natarajan, S ^{[1
]}

机构：

[1] Jawaharlal Nehru Ctr Adv Sci Res, Chem & Phys Mat Unit, Framework Solids Lab, Bangalore 560064, Karnataka, India

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 20期

关键词：

D O I：

10.1039/b204669p

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and single crystal structure of a zinc arsenate, [NH3(CH2)(3)NH2(CH2)(2)NH3][Zn-4(AsO4)(3)(HAsO4)].H2O, I, is presented. The structure of I is built from a network of ZnO4, AsO4 and HAsO4 tetrahedral units, connected through their vertices. The connectivity gives rise to 3-, 4- and 5-membered rings, which are joined together forming a one-dimensional column. The columns are connected forming the inter-connected helical channels bound by 8-T atoms (T = Zn and As) in the bc plane.

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页码：3874 / 3878

页数：5

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