Tandem synthesis of polypropionate chains-highly stereoselective synthesis of the ansa chain of streptovaricin U and protostreptovaricins based on stereospecific methylation of gamma,delta-epoxy acrylates by trimethylaluminium

被引：19

作者：

Miyashita, M ^{[1
]}

Shiratani, T ^{[1
]}

Kawamine, K ^{[1
]}

Hatakeyama, S ^{[1
]}

Irie, H ^{[1
]}

机构：

[1] NAGASAKI UNIV,FAC PHARMACEUT SCI,NAGASAKI 852,JAPAN

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 09期

关键词：

D O I：

10.1039/cc9960001027

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The highly stereoselective synthesis of the ansa chain segment 23 of streptovaricin U and protostreptovaricins (I and II) is achieved by stereospecific methylation of gamma,delta-epoxy acrylates with trimethylaluminium.

引用

页码：1027 / 1028

页数：2

共 17 条

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